张磊，男，讲师，博士
E-mail:zhanglei-chem@tcu.edu.cn
研究方向：化学反应机理的理论模拟、有机发光材料结构和性能的理论研究
教育经历：
2009.09– 2014.07，北京师范大学化学学院，博士，导师：方德彩
2005.09– 2009.07，天津师范大学化学与生命科学学院，学士
科研与学术工作经历：
2017.09–至今，suncitygroup太阳新城，讲师
2014.11– 2017.06，北京师范老员工命科学学院，博士后
主持或参加的科研项目：
1.国家自然科学基金—青年项目，钌催化脱氢偶联反应机理和特殊选择性的理论研究，2021.01 – 2023.12，24万，主持，在研
2.天津市教委课题，金属催化丙二烯参加的环加成反应的理论研究，2019.07 – 2021.07，6万，主持，在研
3.国家自然科学基金—面上项目，高价过渡金属催化反应机理的理论研究，2018.01 – 2021.12，65万元，参加，结题
4.国家自然科学基金—重大研究计划培育项目子课题，长链分子燃烧反应机理和动力学的理论研究，2016.01 – 2018-12，65万元，参加，结题
代表性研究成果：
[1]Zhang L.; Fang, D.-C.* DFTStudies on the Directing Group Dependent Arene–Alkene Cross-Couplings: AreneActivation vs. Alkene Activation.Organic& Biomolecular Chemistry,2015,13, 7950.
[2]Zhang, L.; Fang, D.-C.* AnExplicit Interpretation of the Directing Group Effect for the Pd(OAc)2-CatalyzedAromatic C–H Activations.The Journal ofOrganic Chemistry,2016,81, 7400.
[3]Zhang, L.; Fang, D.-C.*Explicit Roles of Diverse Directing Groups in Determining Transition StateEnergy and Reaction Exothermicity of C−H Activation Pathways.Organic Chemistry Frontiers,2017,4, 1250.
[4]Zhang, L.; Fang, D.-C.* KeyRole of PdIVIntermediates in Promoting PdII-CatalyzedDehydrogenative Homocoupling of Two Arenes: A DFT Study.Organometallics,2017,36, 4943.
[5]Zhang, L.*; Yu, L.; Zhou, J.;Chen, Y.* Meta-Selective C–H Alkylation of 2-Phenylpyridine Catalyzed byRuthenium: DFT Study on the Mechanism and Regioselectivity.European Journal of Organic Chemistry,2018,2018, 5268.
[6]Zhang, L.*; Jiang, B.; Zhou,J.; Yu, L.; Chen, Y.* Preferred C2−H Activation of Quinoline N-Oxides Catalyzedby Palladium Acetate: DFT Study on the Plausible Mechanism andRegioselectivity.ChemistrySelect,2018,3, 11469.
[7]Ding, W.; Yu, A.*;Zhang, L.*;Meng, X.* Construction of Eight-Membered Cyclic Diaryl Sulfides via DominoReaction of Arynes with Thioaurone Analogues and DFT Study on the ReactionMechanism.Organic Letters,2019,21, 9014.
[8]Zhang, L.*; Jiang, B.; Chen,Y.*; Lv, J.-F.; Feng, W.-C. A Computational Study on the Reaction Mechanisms ofNickel-Catalyzed Diarylation of Alkenes.EuropeanJournal of Organic Chemistry,2019,2019, 6217.
[9]Zhou, Y.; Xue, R.-C.; Feng, Y.*;Zhang,L.*How does HOTf/HFIP Cooperative System Catalyze the Ring-OpeningReaction of Cyclopropanes? A DFT Study.AsianJournal of Organic Chemistry,2020,9, 311.
[10]Zi, L.; Zhang, J.; Li, C.; Qu, Y.; Zhen, B.; Liu, X.*;Zhang, L.*Synthesis, Properties, and Reactivity of Bis-BNPhenanthrenes: Stepwise Bromination of the Main Scaffold.Organic Letters,2020,22, 1499.
[11]Zhou, J.; Song, X.-X.; Zhao, C.-B.; Wang, L.-L.; Zhang, X.-Q.; Chen, Y.;Zhang, L.*DFT Study onOxidative Cyclization ofo-AlkynylbenzoatesMediated by Hypervalent Iodine Reagent: Mechanism and Substituent Effect.ChemistrySelect,2020,5, 3113.
[12]Ma, S.; Yu, A.; Zhang, S.*;Zhang, L.*;Meng, X.* Construction of [6-5-5-6-6] Pentacyclic Skeleton via PhosphineCatalyzed Domino Reaction and Mechanism Study.Journal of Organic Chemistry,2020,85, 7884.
[13]刘秉康,陈瑜,刘旭光*,张磊*.硼氮[4]螺烯的合成、表征及光物理性质研究.有机化学,2020,40, 2879.
[14]Shen, J.; Yu, A.*;Zhang, L.*;Meng, X.* Green Construction of Benzothiophene Fused Pyrrolidone in Water viaCatalyst-Free Process and Mechanism Study [J].Green Chem.,2020,22, 6798.
[15]Deng, Q.; Yu, A.*;Zhang, L.*;Meng, X.* Selective Synthesis of Benzothiophene-Fused Polycyclic,Eight-Membered N-Heterocycles via Amine-Mediated Three-Component DominoStrategy [J].Advanced Synthesis &Catalysis,2021,4, 1081.
[16]Zhou, J.; Zhou, Y.; Li, Y.; Zhang, J.;Zhang,L.*DFT Mechanistic Study on Palladium-Catalyzed Redox-NeutralHydroarylation of Unactivated Alkenes with Arylboronic Acids [J].Asian Journal of Organic Chemistry,2021,2, 412.
[17]Dai, Y.; Di, J.; Hao, Z.; Meng, X.*;Zhang,L.*Synthesis of Spiro[benzo[b]thiophene-2(3H),1’-cyclopropan]-3-onesvia Domino Reaction Between Thioaurones and Sulfur Yildes [J].Asian Journal of Organic Chemistry,2021,10, 1449.
[18]Zhang, G.; Yu, A.; Lei, Y.; Meng, X.*;Zhang,L.*Synthesis of novel pyridinium 1,5-zwitterions and their reactivitywith isatin-based α-(trifluoromethyl)imines: a sulfur-controlled dominoreaction [J].Organic Chemistry Frontiers,2021,8, 3718.
